2009년 12월 1일 화요일

Battery Breakthrough?

By Tyler Hamilton
Monday, January 22, 2007


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A secretive Texas startup developing what some are calling a "game changing" energy-storage technology broke its silence this week. It announced that it has reached two production milestones and is on track to ship systems this year for use in electric vehicles.


The ZENN car will be the first commercial application of EEStor's new energy storage system. The company is expecting delivery of the systems later this year.
Credit: ZENN Cars


EEStor's ambitious goal, according to patent documents, is to "replace the electrochemical battery" in almost every application, from hybrid-electric and pure-electric vehicles to laptop computers to utility-scale electricity storage.


The company boldly claims that its system, a kind of battery-ultracapacitor hybrid based on barium-titanate powders, will dramatically outperform the best lithium-ion batteries on the market in terms of energy density, price, charge time, and safety. Pound for pound, it will also pack 10 times the punch of lead-acid batteries at half the cost and without the need for toxic materials or chemicals, according to the company.


The implications are enormous and, for many, unbelievable. Such a breakthrough has the potential to radically transform a transportation sector already flirting with an electric renaissance, improve the performance of intermittent energy sources such as wind and sun, and increase the efficiency and stability of power grids--all while fulfilling an oil-addicted America's quest for energy security.


The breakthrough could also pose a threat to next-generation lithium-ion makers such as Watertown, MA-based A123Systems, which is working on a plug-in hybrid storage system for General Motors, and Reno, NV-based Altair Nanotechnologies, a supplier to all-electric vehicle maker Phoenix Motorcars.


"I get a little skeptical when somebody thinks they've got a silver bullet for every application, because that's just not consistent with reality," says Andrew Burke, an expert on energy systems for transportation at University of California at Davis.


That said, Burke hopes to be proved wrong. "If [the] technology turns out to be better than I think, that doesn't make me sad: it makes me happy."


Richard Weir, EEStor's cofounder and chief executive, says he would prefer to keep a low profile and let the results of his company's innovation speak for themselves. "We're well on our way to doing everything we said," Weir told Technology Review in a rare interview. He has also worked as an electrical engineer at computing giant IBM and at Michigan-based automotive-systems leader TRW.


Much like capacitors, ultracapacitors store energy in an electrical field between two closely spaced conductors, or plates. When voltage is applied, an electric charge builds up on each plate.


Ultracapacitors have many advantages over traditional electrochemical batteries. Unlike batteries, "ultracaps" can completely absorb and release a charge at high rates and in a virtually endless cycle with little degradation.


Where they're weak, however, is with energy storage. Compared with lithium-ion batteries, high-end ultracapacitors on the market today store 25 times less energy per pound.


This is why ultracapacitors, with their ability to release quick jolts of electricity and to absorb this energy just as fast, are ideal today as a complement to batteries or fuel cells in electric-drive vehicles. The power burst that ultracaps provide can assist with stop-start acceleration, and the energy is more efficiently recaptured through regenerative braking--an area in which ultracap maker Maxwell Technologies has seen significant results.

High-Energy Batteries Coming to Market

Rechargeable zinc-air batteries can store three times the energy of a lithium-ion battery.

By Kevin Bullis
Wednesday, October 28, 2009


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A Swiss company says it has developed rechargeable zinc-air batteries that can store three times the energy of lithium ion batteries, by volume, while costing only half as much. ReVolt, of Staefa, Switzerland, plans to sell small "button cell" batteries for hearing aids starting next year and to incorporate its technology into ever larger batteries, introducing cell-phone and electric bicycle batteries in the next few years. It is also starting to develop large-format batteries for electric vehicles.


Battery unpacked: This graphic illustrates the multilayered structure of a ReVolt rechargeable zinc-air battery. From top to bottom: the battery cover, which lets in air; a porous air electrode; the interface between electrodes; the zinc electrode; the casing.
Credit: ReVolt

The battery design is based on technology developed at SINTEF, a research institute in Trondheim, Norway. ReVolt was founded to bring it to market and so far has raised 24 million euros in investment. James McDougall, the company's CEO, says that the technology overcomes the main problem with zinc-air rechargeable batteries--that they typically stop working after relatively few charges. If the technology can be scaled up, zinc-air batteries could make electric vehicles more practical by lowering their costs and increasing their range.

Unlike conventional batteries, which contain all the reactants needed to generate electricity, zinc-air batteries rely on oxygen from the atmosphere to generate current. In the late 1980s they were considered one of the most promising battery technologies because of their high theoretical energy-storage capacity, says Gary Henriksen, manager of the electrochemical energy storage department at Argonne National Laboratory in Illinois. The battery chemistry is also relatively safe because it doesn't require volatile materials, so zinc-air batteries are not prone to catching fire like lithium-ion batteries.

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Because of these advantages, nonrechargeable zinc-air batteries have long been on the market. But making them rechargeable has been a challenge. Inside the battery, a porous "air" electrode draws in oxygen and, with the help of catalysts at the interface between the air and a water-based electrolyte, reduces it to form hydroxyl ions. These travel through an electrolyte to the zinc electrode, where the zinc is oxidized--a reaction that releases electrons to generate a current. For recharging, the process is reversed: zinc oxide is converted back to zinc and oxygen is released at the air electrode. But after repeated charge and discharge cycles, the air electrode can become deactivated, slowing or stopping the oxygen reactions. This can be due, for example, to the liquid electrolyte being gradually pulled too far into the pores, Henriksen says. The battery can also fail if it dries out or if zinc builds up unevenly, forming branch-like structures that create a short circuit between the electrodes.